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首頁 / 專利庫 / 建筑材料 / 堿骨料反應(yīng) / 堿硅酸反應(yīng) / Silicate foam structures and method of preparation

Silicate foam structures and method of preparation

閱讀:665發(fā)布:2023-06-14

專利匯可以提供Silicate foam structures and method of preparation專利檢索,專利查詢,專利分析的服務(wù)。并且A liquid silicate reactant, such as phosphoric acid, is absorbed in an amorphous reactant carrier, preferably calcium containing, to form a dry premix composition that is blended with an aqueous alkali metal silicate to form a moldable silicate mix. This mix is heated in a mold at a temperature sufficient to cause the removal of water therefrom, with small water gas bubbles being formed within and throughout the mix to produce a lightweight multicellular foam structure. The reactant and calcium ions are slowly leached from the carrier for reaction with the silicate during the foaming process, improving the water-insolubility and firmness characteristics of the resulting foamed structure. The rate of leaching is sufficiently slow, however, so as not to cause premature and rapid reaction with the silicate tending to reduce expansion of the structure. As a result, a low density foamed structure having a density of from about 3 to about 15, preferably less than 10, lbs/ft3 is obtained. The aqueous alkali metal silicate preferably comprises a combination of sodium silicate and potassium silicate, with the potassium silicate comprising from about 5 percent to about 10 percent by weight based on the total weight of alkali metal silicate employed.,下面是Silicate foam structures and method of preparation專利的具體信息內(nèi)容。

1. A METHOD FOR PREPARING A FOAMED SILICATE STRUCTURE COMPRISING: A. PREMIXING A HIGHLY ABSORBENT, AMORPHOUS LIGHTWEIGHT REACTANT CARRIER WITH A LIQUID AGENT REACTIVE WITH SILICATE TO IMPROVE THE WATER-SOLUBILITY AND FIRMNESS OF SAID SILICATE UPON FOAMING THEREOF, SAID CARRIER AND SAID AGNET BEING MIXED IN PROPORTIONS SUCH THAT SAID AGENT IS ESSENTIALLY TOTALLY ABSORBED BY THE REACTANT CARRIER, RESULTING IN AN ESSENTIALLY DRY PREMIX COMPOSITION; B. MIXING SAID DRY PREMIX COMPOSITION WITH AN AQUEOUS ALKALI METAL SILICATE HAVING A TOTAL SOLIDS CONTENT OF FROM ABOUT 35 PERCENT TO ABOUT 55 PERCENT BY WEIGHT TO FORM A MOLDABLE SILICATE MIX; C. HEATING SAID MOLDABLE SILICATE MIX IN A MOLD AT A TEMPERATURE SUFFICIENT TO CAUSE THE WATER CONTENT OF THE MIX TO BE RAPIDLY REMOVED THEREFROM, SMALL WATER VAPOR GAS BUBBLES BEING FORMED WITHIN AND THROUGHOUT THE MIX TO PRODUCE A LIGHTWEIGHT, MULTI-CELLULAR FOAM STRUCTURE.
2. The process of claim 1 and including cooling the foamed silicate structure prior to removal thereof from said mold.
3. The process of claim 1 in which said alkali metal silicate comprises sodium silicate.
4. The process of claim 3 in which said alkali metal silicate comprises sodium silicate and potassium silicate.
5. The process of claim 4 in which said potassium silicate comprises from about 5 percent to about 10 percent by weight based on the total weight of alkali metal silicate employed, whereby the strength, dimensional stability, water insolubility and non-hygroscopic character of the foamed silicate structure are enhanced.
6. The process of claim 5 in which said amorphous carrier comprises silica containing from about 5 percent to about 25 percent by weight of an alkaline earth metal salt.
7. The process of claim 6 in which said salt is calcium oxide.
8. The process of claim 5 in which said liquid agent is taken from the group consisting of concentrated phosphoric acid, hydrochloric acid, aluminum chloride, ammonium chloride and aluminum sulfate solution.
9. The process of claim 1 in which the carrier comprises silica, and said silica and said liquid agent are mixed in a weight ratio of 4 parts silica and from 1 to 2 parts of said liquid reactant to form said dry premix composition.
10. The process of claim 8 in which the carrier comprises silica and said silica and said liquid agent are mixed in a weight ratio of 4 parts silica and from 1 to 2 parts of said liquid agent to form said dry premix composition.
11. The process of claim 10 in which said dry premix composition and said alkali metal silicates are blended in a weight ratio of about 10 parts of said dry premix to about 85 to about 95 parts of said silicates to form said moldable silicate mix.
12. The process of claim 8 in which said liquid agent comprises phosphoric acid.
13. The process of claim 11 in which said liquid agent comprises phosphoric acid.
14. The process of claim 13 in which said phosphoric acid comprises 85.5 percent phosphoric acid.
15. The process of claim 1 in which said moldable silicate mix is heated at an air temperature of from about 212*F to about 900*F for a period of time sufficient to permit water to be vaporized from the body of the mix, thus forming the desired foamed structure.
16. The process of claim 15 in which said moldable mix is heated by high-frequency electronic heating, said temperature not exceeding about 240*F, the time of heating not exceeding 15 minutes.
17. The process of claim 5 in which said moldable silicate mix is heated at an air temperature of from about 212*F to about 900*F for a period of time sufficient to permit water to be vaporized from the body of the mix, thus forming the desired foam structure.
18. The process of claim 17 in which said temperature is from about 220*F to about 800*F.
19. The process of claim 18 in which said liquid agent is taken from the group consisting of concentrated phosphoric acid, hydrochloric acid, aluminum chloride, ammonium chloride and aluminum sulfate solution.
20. The process of claim 19 in which said liquid agent comprises 85.5 percent phosphoric acid.
21. The process of claim 20 in which the carrier comprises silica and said silica and said liquid agent are mixed in the proportions of about 4 parts silica and from 1 to 2 parts phosphoric acid by weight to form said dry premix, said premix and alkali metal silicates being blended in a weight ratio of about 10 parts of said dry premix to about 85 to about 95 parts of said silicates to form said moldable silicate mix.
22. A moldable silicate mix composition comprising: a. an aqueous alkali metal silicate having a total solids content of from about 35 percent to about 55 percent by weight; and b. a dry premix composition comprising a mixture of a highly absorbent, amorphous, lightweight carrier comprising amorphous silica containing from about 5 percent to about 25 percent by weight of an alkaline earth metal salt and a liquid agent reactive with silicate to improve the water insolubility and firmness of said silicate upon foaming thereof, said liquid agent being present in an amount such that said agent is essentially totally absorbed by the carrier.
23. The composition of claim 22 in which said alkali metal silicate comprises sodium silicate.
24. The composition of claim 23 in which said alkali metal silicate comprises sodium silicate and potassium silicate.
25. The composition of claim 24 in which said potassium silicate comprises from about 5 percent to about 10 percent by weight based on the total weight of alkali metal silicate employed, whereby the strength, dimensional stability, water insolubility and non-hygroscopic character of the foamed silicate structure are enhanced.
26. The composition of claim 25 in which said metal salt is calcium oxide.
27. The composition of claim 25 in which said liquid agent is taken from the group consisting of concentrated phosphoric acid, hydrochloric acid, aluminum chloride, ammonium chloride and aluminum sulfate solution.
28. The composition of claim 27 in which said amorphous silica carrier and said liquid agent are employed in a weight ratio of 4 parts silica and 1 to 2 parts of said liquid agent to form said dry premix and said dry premix and said aLkali metal silicate are employed in a weight ratio of about 10 parts of said premix to about 85 to about 95 parts of said silicates.
29. The composition of claim 28 in which said liquid agent comprises phosphoric acid.
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